[1]江元汝,张漩卓一,党方方,等.一种新型双Schif碱及配合物的合成[J].西安建筑科技大学学报:自然科学版,2013,45(01):117-120,125.[doi:10.15986/j.1006-7930.2013.01.018]
　JIANG Yuan-ru,ZHANG Xuan-zhuo-yi,DANG Fang-fang,et al.Synthesis and character of the new bis-schiff base and its complexes[J].J.Xi’an Univ. of Arch. & Tech.:Natural Science Edition,2013,45(01):117-120,125.[doi:10.15986/j.1006-7930.2013.01.018]
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一种新型双Schif碱及配合物的合成()
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西安建筑科技大学学报:自然科学版[ISSN:1006-7930/CN:61-1295/TU]

卷:
45
期数:
2013年01期
页码:
117-120,125
栏目:
出版日期:
2013-02-28

文章信息/Info

Title:
Synthesis and character of the new bis-schiff base and its complexes
文章编号:
1006-7930(2013)01-0117-04
作者:
江元汝; 张漩卓一; 党方方; 陈利君
(西安建筑科技大学理学院,陕西 西安 710055)
Author(s):
JIANG Yuan-ru;  ZHANG Xuan-zhuo-yi;  DANG Fang-fang;  CHEN Li-jun
(School of Science, Xian University of Architecture and Technology, Xian 710055,China)
关键词:
双Schif碱; 邻苯二甲醛; 氨基硫脲
Keywords:
bis-Schiff base;  OPA;  thiosemicarbazide
分类号:
O625
DOI:
10.15986/j.1006-7930.2013.01.018
文献标志码:
A
摘要:
Schif碱及过渡金属配合物是一类具有优异的光谱学特性、应用广泛的多功能化合物.以邻苯二甲醛和氨基硫脲为单体,合成了邻苯二甲醛缩氨基硫脲Schif碱配体(H2L),利用该配体与铜(Ⅱ)和钴(Ⅱ)、镍(Ⅱ)、锰(Ⅱ)、锌(Ⅱ)形成配合物并用红外光谱、核磁等方法进行了表征.结果表明:邻苯二甲醛和氨基硫脲生成了一种新型的具有对称结构的双希夫碱配体,这种新型配体与过渡金属铜(Ⅱ)和钴(Ⅱ)、镍(Ⅱ)、锰(Ⅱ)、锌(Ⅱ)按照硫醇式进行配位,生成了具有双桥结构的邻苯二甲醛双缩氨基硫脲合铜(Ⅱ),邻苯二甲醛双缩氨基硫脲合锌(Ⅱ)等几个新配合物
Abstract:
Schiff base and its complexes have special structure and properties. A symmetrical OPA-diaminothourea schiff base ligand is synthesized by OPA and aminothiourea under different conditions, and its complexes of copper(Ⅱ),cobalt(Ⅲ),nickel(Ⅱ),manganese(Ⅱ)and zinc(Ⅱ)are synthesized. The structures of the ligand and its complexes were characterized by IR, MAR. The melting point and then solubility of the metal complexes were determined. The results show that the new mixed-ligand are OPA- diaminothiourea Schiff Base and the metal complexes are sulphur-containing bis-Schiff bases

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备注/Memo

备注/Memo:
收稿日期:2012-04-09 修改稿日期:2013-01-13
基金项目:国家自然科学基金资助项目(21205092)
作者简介:江元汝(1960-),女,湖北宜昌人,教授,主要从事功能材料化学方面的教学与科研工作.
更新日期/Last Update: 2015-10-05