[1]宋学锋,朱娟娟.粉煤灰-矿渣复合基地质聚合物力学性能的影响因素[J].西安建筑科技大学学报:自然版,2016,48(01):128-132.[doi:10.15986/j.1006-7930.2016.01.021]
 SONG Xuefeng,ZHU Juanjuan.The factors affecting the mechanical properties of fly ash and slag based geopolymer[J].J.Xi’an Univ. of Arch. & Tech.:Natural Science Edition,2016,48(01):128-132.[doi:10.15986/j.1006-7930.2016.01.021]
点击复制

粉煤灰-矿渣复合基地质聚合物力学性能的影响因素()
分享到:

西安建筑科技大学学报:自然版[ISSN:1006-7930/CN:61-1295/TU]

卷:
48
期数:
2016年01期
页码:
128-132
栏目:
出版日期:
2016-02-28

文章信息/Info

Title:
The factors affecting the mechanical properties of fly ash and slag based geopolymer
文章编号:
1006-7930(2016)01-0128-05
作者:
宋学锋朱娟娟
西安建筑科技大学材料与矿资学院,陕西 西安 710055
Author(s):
SONG Xuefeng ZHU Juanjuan
School of Materials & Mineral Resources, Xi′an Univ. of Arch. & Tech., Xi′an 710055, China
关键词:
粉煤灰地质聚合物胶凝材料抗压强度
Keywords:
fly ash geopolymer cementitious materials compressive strength
分类号:
TU528.2
DOI:
10.15986/j.1006-7930.2016.01.021
文献标志码:
A
摘要:
地质聚合物作为一种新型的绿色胶凝材料,与硅酸盐水泥相比,地质聚合物具有环境友好、耐高温、耐久性好等优点.本实验采用工业固体废物粉煤灰和矿渣,配以石英砂和碱硅酸盐激发剂,制备得到地质聚合物材料.以制品抗压强度为指标,研究了粉煤灰与矿渣复合比、碱硅酸盐激发剂的模数与固含量、以及液胶比对地质聚合物性能的影响规律.结果表明:随着粉煤灰占总胶凝材料比例的增加,体系中CaO 的含量降低,地质聚合物的抗压强度逐渐降低;当碱硅酸盐激发剂固含量为32%时,地聚物抗压强度随其模数的增大表现为先增大后减小,当模数为1.2 时,试样7 d 抗压强度达到94.9 MPa;对于液胶比,随液胶比的增大,地聚物的抗压强度先增大后减小,液胶比为0.48 时,抗压强度最大.
Abstract:
Geopolymer is a new type of green cementitious materials, compared with Portland cement, geopolymer has many excellent properties, such as environment friendly, high temperature resistance, good durability, etc. In this experiment, geopolymer materials was prepared by the industrial solid wastes fly ash and slag, with quartz sand and alkali silicate activator. The compressive strength of the products as the index and the influence of the fly ash and slag composite ratio, liquid-binder ratio, modulus of alkali silicate activator and solid cotent on the properties of geopolymer were investigated. The results indicated that the compressive strength of geopolymer decreased gradually with the increase of the proportion of the fly ash of the total cementitious material; With the increase of the modulus, the compressive strength of geopolymer increased at first and then decrease when the solid content of alkali silicate activator is 32%; When the modulus of activator was 1.2,the 7d compressive strength of the products was reached 94.4MPa.For liquid-binder ratio, with the increase of the ratio of liquid to binder, thecompressive strength of the products first increase and gradually decrease. When the ratio of liquid to binder was 0.48, the compressive strength of the products was the largest.

参考文献/References:

[1] DAVIDOVITS J. 30 years of successes and failures in geopolymer application, market trends and potential breakthroughs[C]//Geopolymer 2002 Conference, Australia: Melbourne, 2002, 10: 28-29.
[2] 赵素宁, 曲烈, 杨久俊, 等. 粉煤灰地聚物的力学性能及微观结构研究[J]. 粉煤灰, 2010, 3(5): 3-6.
ZHAO Suning, QU Lie, YANG Jiujun, et al. Study on the mechanical properties and microstrcture of fly ash-based geopolymer[J].Fly ash,2010,3(5):3-6.
[3] BAKHAREV T. Geopolymeric materials prepared using class f fly ash and elevated temperature curing[J].Cement and Concrete Research, 2005,35(6): 1224-1232.
[4] Davidovits J. Synthetic mineral polymer compound of the silicoaluminates family and preparation process[P].US:Pat4472199, 1984.09.18.
[5] van Jaarsveld JGS, Lukey GC, van Deventer JSJ, et al. The stabilization of mine tailings by reactive geopolymerization. Publ Australas Inst Min Metall, 2000,5: 363-371.
[6] DAVIDOVITS J. Geopolymer:inorganic polymeric new materials[J].J Materials Education,1994a,16:91-138.
[7] PHAIR J W, Van DEVENTER J S J.Effect of silicate activator PH on the leaching and material characteristics of waste-based inorganic polymers[J].Miner Eng, 2001,14: 289-304.
[8] LEE W K W, DEVENTER J S J V. The effect of ionic contam inants on the early-age properties of alkali-activated fly ash-based cements[J].Cement and Concrete Research, 2002,32:577-584.
[9] GABORIAUD F, NONAT A, CHAUMONT D, et al. Aggregation and gel formation in basic silico-calco-alkaline solutions studies:a SAXS,SANS and ELS study[J].J Physcal Chemistry B, 1999,103: 5775-5781.
[10] XU H, VAN DEVENTER J S J. The geopolymerization of alumino-silicate minerals[J].Int J Miner Process, 2002,59: 247-266.
[11] 曹德光, 苏打根, 宋国胜. 低模数硅酸钠溶液的结构及其键合反应特性[J].硅酸盐学报,2004,32(8):1036-1039.
CAO Deguang, SU Dagen, SONG Guosheng. Geopolymeric behavior and structure of lower modulus sodium silicate solutions[J].Journal of the Chinese ceramic society, 2004,32(8):1036-1039.

相似文献/References:

[1]于本田,王起才,周立霞,等.兰新铁路第二双线混凝土矿物掺合料掺量优化试验研究[J].西安建筑科技大学学报:自然版,2012,44(03):351.[doi:10.15986/j.1006-7930.2012.03.008]
 YU Ben-tian,WANG Qi-cai,ZHOU Li-xia,et al.Optimization research on the contents of mineral admixture of concrete in the 2nd double line of Lanzhou-Xinjiang Railway[J].J.Xi’an Univ. of Arch. & Tech.:Natural Science Edition,2012,44(01):351.[doi:10.15986/j.1006-7930.2012.03.008]
[2]李国新,张 歌,史 琛,等.膨胀剂在大体积混凝土环境下的膨胀效能研究[J].西安建筑科技大学学报:自然版,2016,48(02):289.[doi:10.15986/j.1006-7930.2016.02.025]
 LI Guoxin,ZHANG Ge,SHI Chen,et al.The effects of fly ash dosage and adding gypsum on the expansion effect of expansive agent at simulation large volume concrete environment[J].J.Xi’an Univ. of Arch. & Tech.:Natural Science Edition,2016,48(01):289.[doi:10.15986/j.1006-7930.2016.02.025]
[3]史 琛,何廷树,李益民,等.粉煤灰对硅酸盐水泥-铝酸盐水泥-石膏三元体系性能的影响[J].西安建筑科技大学学报:自然版,2016,48(03):459.[doi:10.15986/j.1006-7930.2016.03.026]
 SHI Chen,HE Tingshu,LI Yimin,et al.Effects of fly ash on the performances of portland cement- aluminate cement - gypsum ternary cementitious system[J].J.Xi’an Univ. of Arch. & Tech.:Natural Science Edition,2016,48(01):459.[doi:10.15986/j.1006-7930.2016.03.026]
[4]吴耀鹏,李晓蕾,姜厚文,等.不同配合比再生混凝土高温后的残余抗压强度[J].西安建筑科技大学学报:自然版,2017,49(03):375.[doi:10.15986/j.1006-7930.2017.03.010]
 WU Yaopeng,LI Xiaolei,JIANG Houwen,et al.Residual compressive strength of recycled aggregate concrete with the different mixture ratio after high temperature[J].J.Xi’an Univ. of Arch. & Tech.:Natural Science Edition,2017,49(01):375.[doi:10.15986/j.1006-7930.2017.03.010]
[5]李东,朱月圆,耿健,等.矿物掺合料和CLDH对水泥基材料氯离子固化性能研究[J].西安建筑科技大学学报:自然版,2019,51(03):344.[doi:10.15986/j.1006-7930.2019.03.006]
 LI Dong,ZHU Yueyuan,GENG Jian,et al.A study on curing charateristics of chloride ions binding in cement based materials with mineral admixture and CLDH[J].J.Xi’an Univ. of Arch. & Tech.:Natural Science Edition,2019,51(01):344.[doi:10.15986/j.1006-7930.2019.03.006]
[6]刘文丰,李碧雄,王熠泽,等.稻壳灰粒径对水泥砂浆的碱硅酸反应风险影响[J].西安建筑科技大学学报:自然版,2024,56(01):30.[doi:10.15986/j.1006-7930.2024.01.005]
 LIU Wenfeng,LI Bixiong,WANG Yize,et al.Effect of rice husk ash particle size on alkali silica reaction risk of cement mortar[J].J.Xi’an Univ. of Arch. & Tech.:Natural Science Edition,2024,56(01):30.[doi:10.15986/j.1006-7930.2024.01.005]

备注/Memo

备注/Memo:
收稿日期:2015-07-28 修改稿日期:2016-01-26
基金项目:陕西省自然科学基金资助项目(2013JQ6015);陕西省住建厅基金资助项目(2015-K86)
作者简介:宋学锋(1976-),男,博士,教授,主要从事先进水泥基材料方面研究.E-mail:songxuefeng@xauat.edu.cn
更新日期/Last Update: 2016-04-02